Citation: Yong Zhi WANG, Hai Feng JI, Chen Ho TUNG, Gui Chun YUE. Interaction of Polyelectrolyte with Fluorocarbon Surfactant in Aqueous Solution[J]. Chinese Chemical Letters, ;1996, 7(10): 951-953. shu

Interaction of Polyelectrolyte with Fluorocarbon Surfactant in Aqueous Solution

a Institute of Photographic Chemistry Chinese Academy of Sciences Beijing 100101;
b Department of Environmental Sciences Jilin University

Received Date: 8 March 1996

Fund Project: This project was supported by the National Natural Science Foundation of China

The variation of the I₁/I₃ ratio of the fluorescence of pyrene in polystyrene-based quaternary ammonium salt (PA) and sodium carboxymethylamylose (NaCMA) aqueous solutions was measured as a function of sodium perfluorooctanoate (SPFO) concentration.Association of the anionic fluorocarbon surfactant with cationic polyelectrolyte (PA) to form mixed micelles occurred at the surfactant concentrations far below its normal critical concentration, while no interaction between SPFO and anionic polyelectrolyte (NaCMA) was detected.The driving force for the formation of mixed micelles of SPFO and PA is electrostatic interactions.
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