Citation: Bin YE, Jin Li ZHANG, Ming Qing CHEN, Yu Lin WU. SYNTHESIS OF 1, 6-DIEPI-DIHYDROARTEANNUIC ACID[J]. Chinese Chemical Letters, ;1990, 1(1): 65-68. shu

SYNTHESIS OF 1, 6-DIEPI-DIHYDROARTEANNUIC ACID

a Shanghai Institute of Organic Chemistry Academia Sinica Shanghai 200032;
b Research Center of Analysis and Measurement Fudan University

Received Date: 13 December 1989

R(+)-Citronellal was converted into a key intermediate, (unsaturated ketone 5)in three steps, which led to 6 having the frame of arteannuic acid through intramolecular ene reaction.Further modification of 6afforded 1, 6-epimer of dihydroarteannuic acid.The configuration of 7 was determined by X-ray diffraction analysis.
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