Citation: Shen Yang TONG, Li NA. SPECTROPHOTOMETRIC STUDY OF DDQ CHARGE-TRANSFER COMPLEXES WITH 1,10-PHENANTHROLINE AND ITS DERIVATIVES[J]. Chinese Chemical Letters, ;1992, 3(3): 201-204. shu

SPECTROPHOTOMETRIC STUDY OF DDQ CHARGE-TRANSFER COMPLEXES WITH 1,10-PHENANTHROLINE AND ITS DERIVATIVES

Shen Yang TONG ,
Li NA

Department of Chemistry, Peking University, Beijing 100871

Received Date: 20 November 1991

1,10-phenanthroline and its derivatives can form charge-transfer complexes with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ).The absorption spectra and conditions of complex formation,such as the reaction time,the quantity of DDQ, and the solvents, have been studied.After the HMO calculation of phenanthrolines,the molar absorptivities were found to depend on the substituents on the phenanthroline rings.
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