Citation: TSUCHIDA Eishun, MIYATAKE Kenji. NOVEL SYNTHESIS OF POLYARYLENESULFONIUM CATIONS THROUGH A MULTI-ELECTRON TRANSFER PROCESS*[J]. Chinese Journal of Polymer Science, ;1998, 16(2): 106-116. shu

NOVEL SYNTHESIS OF POLYARYLENESULFONIUM CATIONS THROUGH A MULTI-ELECTRON TRANSFER PROCESS*

Received Date: 20 December 1997

The oxidative polymerization of aryl sulfoxides provides a novel polysulfo-nium compound, poly(methylsulfonio-1,4-phenylenethio-1,4-phenylene cation) in quantita-tive yield. The polymerization proceeds efficiently in an acidic solution under atmosphericconditions. Oxygen, chemical and electrochemical oxidations are available. Vanadyl acety-lacetonate and cerium ammonium nitrate act as an effective catalyst for the oxygen ox-idative polymerization. The polymerization mechanism involves multielectron oxidation of the sulfides followed by successive electrophilic substitution.The resulting polyarylenesulfonium cations are useful as a soluble precursor for the synthesis of high molecular weight (Mw>105)poly(thio arylne)s.
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