Citation: Kai LIU, Yong GUO, Jian XU, Shi Jun SHAO, Sheng Xiang JIANG. New Subsidiary Interaction Mode of Counteranions with the Periphery Cavity of Calix[4]pyrroles Binding with the Anion Subunits[J]. Chinese Chemical Letters, ;2006, 17(3): 387-390. shu

New Subsidiary Interaction Mode of Counteranions with the Periphery Cavity of Calix[4]pyrroles Binding with the Anion Subunits

Kai LIU ^1,2, ,
Yong GUO ¹ ,
Jian XU ¹ ,
Shi Jun SHAO ¹ ,
Sheng Xiang JIANG ¹

1.
Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000;
2.
Graduate School of the Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100039

Received Date: 22 August 2005

Fund Project: This work was supported by the National Natural Science Foundation of China (No.20372067).

The solution binding properties of calix[4]pyrroles with anion (as tetraalkylammonium salts) were investigated using UV-Vis spectroscopic techniques. The obvious red-shift of absorption maximum band of calix[4]pyrrole in EtOH in the presence of the tetramethylammonium (TMA⁺) salts or tetraethylammonium (TEA⁺) salts were observed, due to the charge-transfer interactions between the electron-rich pyrrole rings of calix[4]pyrroles and TMA⁺ or TEA⁺ cation subunit. The results indicated that calix[4]pyrrole receptors, which link the anionic species through multiple hydrogen bonding interactions, can use the periphery cavity for selectively binding cation subunits by cation-π charge-transfer interaction. The subsidiary interaction mode helps to further stabilize the calix[4]pyrrole-anion complex.
- Anion recognition,
- calix[4]pyrrole,
- charge-transfer interactions,
- tetraalkylammonium salts
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