Citation: Yu Qian SU, Ming Yu NIU, Shu Xia CAO, Jian Chen ZHANG, Yu Fen ZHAO. Intermolecular Phosphoryl Transfer Between Serine and Histidine Residues[J]. Chinese Chemical Letters, ;2004, 15(11): 1289-1291. shu

Intermolecular Phosphoryl Transfer Between Serine and Histidine Residues

1.
The Key Laboratory of Chemical Biology, Department of Chemistry, Zhengzhou University, Zhengzhou 450052;
2.
The Key Laboratory for Bioorganic Phosphorus Chemistry and Chemical Biology, Ministry of Education, Department of Chemistry, School of Life Science and Engineering, Tsinghua University, Beijing 100084

Received Date: 17 September 2003

Fund Project: We thank the Action Plan for the Promoting Education Facing 21th Century of the Chinese Ministry of Education and the National Natural Science Foundation of China (No. 20132020).

A novel intermolecular phosphoryl transfer from O-trimethylsilyl-N-(O, O-diisopropyl) phosphoryl serine trimethylsilyl ester to N, N'-bis(trimethylsilyl) histidine trimethylsilyl ester was studied through electrospray ionization mass spectrometry (ESI-MS). It was proposed that the transfer reaction went through penta-coordinated phosphorus intermediate.
- Intermolecular phosphoryl transfer,
- penta-coordinated phosphorus,
- ESI-MS
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