Citation: Yu Peng TIAN, Jie Ying WU, Fu Xin XIE, Shi Sheng NI. New Complex Nonlinear optical Crystal-Bis(4-methoxybenzaldehyde thiosemicarbazone) Zinc Chloride(ZnL₂Cl₂)[J]. Chinese Chemical Letters, ;1998, 9(2): 215-217. shu

New Complex Nonlinear optical Crystal-Bis(4-methoxybenzaldehyde thiosemicarbazone) Zinc Chloride(ZnL₂Cl₂)

Yu Peng TIAN ^a,b ,
Jie Ying WU ^a,b ,
Fu Xin XIE ^a,b ,
Shi Sheng NI ^a,b

a Department of Chemistry, Anhui University, Hefei 230093;
b Coordination Chemistry Institute, State Key Laboratory of Nanjing University. Nanjing 210093

Received Date: 23 October 1997

Fund Project: This work was supported by the Natural Science Foundation of Anhui and the Educational Committee Foundation of Anhui.

The structure of ZnL₂Cl₂(L=4-methoxybenzaldehyde thiosemicarbazone) has been obtained by x-ray diffraction. The compound crystallized in space group Cc with Z=4, in a unit cell of dimensions, a=9.08909(10), b=22.1420(10), c=11.7890(10)Å; β=90.050(10)°, v=2374.6(12)Å³, Dc=1.552gcm^-3. μ=1.463mm^-1, R=0.0338, and Rw=0.0418. The structure contains individual ZnL₂Cl₂ distorted tetrahedral units in which L molecules are S-bonded as monodentate to the metal ions; chloride ions are also coordinated. The nonlinear optical properties of the zinc complex are also presented in this letter.
- zinc complex-nonlinear optical crystal,
- thiosemicarbazone derivative
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