Citation: Wei Zhong ZHENG, Wen WAN, Fu Jiang DING, Liang Fu ZHANG. The Activation and Carbonylation of the C-Cl Bond Catalyzed by Transition-Metal Complexes[J]. Chinese Chemical Letters, ;1998, 9(4): 345-346. shu

The Activation and Carbonylation of the C-Cl Bond Catalyzed by Transition-Metal Complexes

a Chengdu Institute of Organic Chemistry, Academia Sinica, P. O. Box 415, Chengdu 610041;
b Laboratory of Organomctallic Chemistry, Shanghai Institute of Organic Chemstry, Academia Sinica, Shanghai 20003

Received Date: 3 November 1997

Fund Project: This project (29673041) was supported by NSFC.

Diethyl malonate was synthesized by transition-metal catalyzed alkoxycarbonylation of ethyl chloroacetate. The results show that the conversion of ethyl chloroacetate is greater than 92%, and the selectivity to diethyl malonate is 67.5%.
- diaminoanthraquinone,
- absorption,
- pigment
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