Citation: Zhan Jiang LI, Cheng Fang YU, Meng Shen CAI. STUDIES ON GLYCOSIDES Ⅷ.TOTAL SYNTHESIS OF NEW ALKALOID GLYCOSIDES FROM SELAGINELLA DOEDERIENⅡ[J]. Chinese Chemical Letters, ;1990, 1(3): 213-214. shu

STUDIES ON GLYCOSIDES Ⅷ.TOTAL SYNTHESIS OF NEW ALKALOID GLYCOSIDES FROM SELAGINELLA DOEDERIENⅡ

Department of Organic Chemistry School of Pharmaceutical Sciences Beijing Medical University Beijing 100083

Received Date: 26 March 1990

Two new alkaloids, hordenine-O-α-L-rhamnopyranoside(Ⅰ)and hordenine-0-(6"-trans-cinnamoyl)-4'-O-β-D-glucopyranosyl-α-L-rhamnopyranoside (Ⅲ) isolated from Selaginella doederleinii have been synthesized the first time.A new method, in which trifluoroacetoxyl group was used both as a good leaving group and a protecting group for synthesis of O-glycosides with high stereo-selectivity was reported.
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