Citation: Ge MENG, Ling ZHAO, You Fu LUO, Fen Er CHEN. Studies on a New Usage of Hypophosphorous Acid-iodine System in N-C Bond Cleavage[J]. Chinese Chemical Letters, ;2003, 14(4): 351-354. shu

Studies on a New Usage of Hypophosphorous Acid-iodine System in N-C Bond Cleavage

Department of Chemistry, Fudan University, Shanghai 200433

Received Date: 27 May 2002

A mixture of hypophosphorous acid (H₃PO₂) and iodine in acetic acid can cleave the N-alkyl bond in a variety of N-1 substituted pyrimidine derivative in relatively high yields, withoutany damage to the amido bond in the non-nucleosides pyrimidine base skeleton.
- Hypophosphorous acid,
- iodine,
- carbon-nitrogen bond cleavage
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