Citation: Yi Hui XU, Li LIN, Jia Gang LUO, Boon K. TEO, Zong Ju XIA, Ying Hua ZOU, Hut Ying CHEN. Ultrafast Optical Kerr Effect of ConjugatedSilver Phenylacetylide Complex Oligomer[J]. Chinese Chemical Letters, ;1999, 10(9): 793-794. shu

Ultrafast Optical Kerr Effect of ConjugatedSilver Phenylacetylide Complex Oligomer

1.
Department of Chemistry, University of Hinois at Chicago, Chicago, IL 60680, USA;
2.
Department of Physics, Mesoscopic Physics Laboratory, Peking University, Beijing 100871;
3.
Institute of Polymer Science, Department of Chemistry, Peking University, Beijing 100871

Received Date: 21 May 1999

Silver phenylacetylide oligomer was found to exhibit prominent third-orde,nonlinear optical property. with susceptibility χ⁽³⁾ of 2.4×10^-4 esu (10^-14 mol/L in 1:1 dimethyl sulfoxide/CHCl₃ mixed solution) and second-order hyperpolarizability γ of 5.18×10^-32 esu via heterodyned ultrafast optical Kerr et}feet measurement. It existed mainly as 1:1 complex oligomers and polymers as characterized by mass spectroscopy and elemental analysis etc.
- Silver phenylacetylide,
- conjugated complex,
- optical Kerr effect
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