Citation: Meng ZHANG, Da Li YIN, Ji Yu GUO, Xiao Tian LIANG. An Unusual Formation of Cyclic Sulfite at C-4 and C-5 Positions of Taxane[J]. Chinese Chemical Letters, ;2004, 15(9): 1033-1035. shu

An Unusual Formation of Cyclic Sulfite at C-4 and C-5 Positions of Taxane

Institute of Materia Medica, Chinese Academy of Medical Science & Peking Union Medical College, Beijing 100050

Received Date: 29 July 2003

Fund Project: This research work was financially supported by NNSFC grant No.3977082 and No.30100230.

An unusual formation of cyclic sulfite at C-4 and C-5 positions of taxane was accomplished by treatment of compound 1 with excess MeSO₂Cl/Et₃N and a possible mechanism was proposed.
- Paclitaxel,
- taxane,
- mesylation
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