Citation: Zhi Hui LU, Xue You ZHU, Wei Shan ZHOU. CATALYTIC ASYMMETRIC EPOXIDATION OF α-FURFURYLAMINE IN THE PRESENCE OF MOLECULAR SIEVE AND CaH₂[J]. Chinese Chemical Letters, ;1994, 5(7): 567-568. shu

CATALYTIC ASYMMETRIC EPOXIDATION OF α-FURFURYLAMINE IN THE PRESENCE OF MOLECULAR SIEVE AND CaH₂

1.
Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fengling Lu, Shanghai 200032;
2.
Department of Bio-engineering Sichuan University, Chengdu 610064

Received Date: 9 May 1994

The modified procedure of the catalytic asymmetric epoxidation of the α-furfurylamines (dl)-1a-d in the presence of molecular sieve and CaH₂ provides the slow-reacting enantiomers (S)-1a-d and the fast-reacting enantiomers (2R.6S)-2a-d in high enantioselectivity and high chemical yield.
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