Citation: Xin Cheng LI, Gui Ling NING, Liang Ping WU, Ji Hong SHAN, Yuan LIN. Silver(I)-promoted Oxidation and Ring-enlargement Reactions of Unstrained Hydrocarbons, Polyphenyl-cyclopentadiene[J]. Chinese Chemical Letters, ;2002, 13(12): 1141-1142. shu

Silver(I)-promoted Oxidation and Ring-enlargement Reactions of Unstrained Hydrocarbons, Polyphenyl-cyclopentadiene

1.
School of Chemical Engineering, Dalian University of Technology, Dalian 116012;
2.
Chemistry Department, East China Normal University, Shanghai 200062

Received Date: 30 December 2001

Fund Project: This work was supported by the National Natural Science Foundation of China (No.20072003).

A unique sliver (I)-promoted oxidation reaction of polyphenyl-cyclopentadiene is described, in which an oxygen is inserted into the cyclopentadiene-ring, forming a six-membered pyrylium cation.
- Oxidation,
- pyrylium,
- bond activity,
- polyphenyl-cyclopentadiene
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