Citation: Xiao Mei WANG, Guang Yong ZHOU, Wen Tao YU, Min Hua JIANG. Synthesis, Structure of a Symmetrically Substituted Stilbene with Strong Two-photon Absorption and Up-converted Blue Fluorescence[J]. Chinese Chemical Letters, ;2001, 12(11): 1001-1004. shu

Synthesis, Structure of a Symmetrically Substituted Stilbene with Strong Two-photon Absorption and Up-converted Blue Fluorescence

State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100

Received Date: 28 February 2001

Fund Project: This work was supported by the grant for State Key Program of China.

Efficient Ti-catalyzed reductive coupling methodology was first employed to synthesize the symmetrical bis-donor stilbene, trans-4, 4'-bis[diphenyl amino] stilbene (BDPAS). X-ray diffraction analyses reveal that this new crystal belongs to the triclinic crystal system of centro-symmetric P-1 space group. The DBPAS solution, with the linear transmission at wavelength of ≥450 nm, possesses large two-photon absorption cross section as high as 39.4×10^-48 cm·s/photon resulting in strong two-photon induced blue fluorescence of 460 nm, pumped by 740 nm laser irradiation.
- Symmetrical bis-donor stilbene,
- synthesis,
- crystal structure,
- two-photon absorption,
- two-photon-induced fluorescence
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