Citation: Ya Dong LU, Yan Hua WANG, Zi Lin JIN. Thermoregulated Organic Biphasic Hydrogenation of 1-OcteneCatalyzed by Ru/PETPP Complex[J]. Chinese Chemical Letters, ;2006, 17(2): 255-257. shu

Thermoregulated Organic Biphasic Hydrogenation of 1-OcteneCatalyzed by Ru/PETPP Complex

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012

Received Date: 6 June 2005

Fund Project: The authors are grateful to the financial support from the National Natural Science Foundation of China (Grant no. 20376013), the Fok Ying Tung Education Foundation (Grant no. 91071) and the Doctorate Program Foundation of Higher Education (Grant no. 20020141004).

Thermoregulated organic biphasic system composed of triethylene glycol monomethyl ether (TGME) and n-heptane was first applied to the hydrogenation of 1-octene. Under the optimal conditions: P(H₂)=5.0MPa, T=80℃, t=3h, 1-octene/Ru=1000(molar ratio), the yield of n-octane reached up to 99.6%. Furthermore, the simply decanted catalyst could be reused for 10 times without apparent loss of catalytic activity.
- Thermoregulated organic biphasic system,
- hydrogenation,
- 1-octene,
- ruthenium
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