Citation: Zhi Qiang ZHANG, Zheng Hua TIAN. Nucleophilic Aromatic Substitution of Nitrobenzenes with Nitrite Ion[J]. Chinese Chemical Letters, ;1997, 8(3): 193-194. shu

Nucleophilic Aromatic Substitution of Nitrobenzenes with Nitrite Ion

Anshan Institute of Iron & Steel Technology, Anshan 114002

Received Date: 14 October 1996

It is experimentally found that different reaction courses exist when nitrite ion reacts with nitrobenzenes with different electron withdrawing groups.When it is substituted with strong electron withdrawing groups.self-condensation in aprotic polar solvent occurs to give symmetrical disubstituted diphenyl ethers.However.when it is substituted with moderate electron withdrawing groups,no diphenyl ethers are obtained under the same conditions,instead,corresponding carboxylates are yielded.As a result,the applicability of this reaction is distinctly clarified.
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