Citation: Yan An GAO, Zhong Ni WANG, Jin ZHANG, Wan Guo HOU, Gan Zuo LI, Bu Xing HAN, Feng Feng Lü, Gao Yong ZHANG. Study on the Surface Property of Surfactant Ionic Liquids Solutions[J]. Chinese Chemical Letters, ;2005, 16(7): 963-966. shu

Study on the Surface Property of Surfactant Ionic Liquids Solutions

1.
Key Laboratory of Colloid and Interface Chemistry (Shandong University), Ministry of Education, Jinan 250100;
2.
Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080;
3.
China Research Institute of Daily Chemical Industry, Taiyuan 030001

Received Date: 16 August 2004

Fund Project: This project was supported by the National Natural Science Foundation of China (No. 30370945), Ministry of Science and Technology (2003CCA02900) and Guizhou Provincial Governor Foundation (No. 6, 2001).

The surfactant TX-100 can be dissolved in ionic liquid bmimPF₆ and decrease the surface tension of 1-butyl-3-methylimidazolium hexafluorophosphate (bmimPF₆) solutions. Here,we confirmed that in this new system, the pure solvents need rearrangement at the air-water interface at the initial stage. The dynamic surface tension (DST) study shows that at the initial adsorption stage, the adsorption model of surfactant accords with the diffusion-controlled adsorption mechanism, and the dilute ionic liquids solutions is further close to the diffusion-controlled adsorption.
- Dynamic surface tension,
- ionic liquids,
- adsorption
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