Citation: Xin Guo YANG, Jing Zhi SUN, Han Ying LI, Jian CAO, Mang WANG. Fluorescence Switch Based on a Porphyrin-perylene Dyad[J]. Chinese Chemical Letters, ;2005, 16(2): 257-260. shu

Fluorescence Switch Based on a Porphyrin-perylene Dyad

1.
Department of Polymer Science & Engineering and State Key Laboratory for Silicon Materials, Zhejiang University, Hangzhou 310027;
2.
College of Materials Science and Engineering, Hunan University, Changsha 410082

Received Date: 21 November 2003

Fund Project: This research was supported by the National Natural Science Foundation of China (Grant No. 50073018) and the authors are also thankful to the support from the Key Laboratory of Supramolecular Structure and Materials in Jilin University.

Upon excitation of porphyrin or perylene subunit, the porphyrin-perylene dyad exhibits reversible fluorescence emitting and quenching by formation and neutralization of the protonated porphyrin subunit, thereby providing a prototype of molecular fluorescence switch working in an expanded spectral range.
- Molecular arrays,
- fluorescence switch,
- protonation.
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