Citation: Zi Cheng LI, Ning JIANG, Shu Hua CHEN, Ding LU. A New Method for Synthesis of Methyl 3-Azido-3-deoxy-2-O-mesyl-5-O-benzoylxylofuranoside[J]. Chinese Chemical Letters, ;2002, 13(3): 195-198. shu

A New Method for Synthesis of Methyl 3-Azido-3-deoxy-2-O-mesyl-5-O-benzoylxylofuranoside

1.
Faculty of Chemistry, Sichuan University, Chengdu 610064;
2.
Sichuan Industrial Institute of Antibiotics, Chengdu 610051;
3.
Chengdu Molecule Laboratory, Hengdian Group, Chengdu 610041

Received Date: 14 June 2001

A new method for synthesis of 3-azido-3-deoxyxylofuranoside was described. D-ribose was methylated, then treated with methanesulfonyl chloride to give Ⅱ. Ⅱ was selectively replaced by benzoate at the 5-position to give Ⅲ. All these processes gave good yields. Ⅲ was treated with sodium azide to afford Ⅳ, whose structure was determined by ¹H NMR and ¹³C NMR.
- Xylose derivative,
- nucleoside,
- synthesis
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