Citation: Jin Tang DU, Yan Mei LI, Zhong Zhou CHEN, Shi Zhong LUO, Yu Fen ZHAO. The Self-catalytic Esterification Reaction of O-Phosphoryl Serine Derivative[J]. Chinese Chemical Letters, ;2005, 16(7): 856-858. shu

The Self-catalytic Esterification Reaction of O-Phosphoryl Serine Derivative

Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084

Received Date: 12 July 2004

Fund Project: The authors would like to thank the financial supports from the National Natural Science Foundation of China (No. 20272032 and No. 20320130046), Ministry of Education of China and Tsinghua University.

O-Phosphoryl serine derivative can perform self-catalytic esterification reaction in the mixture of CH₃OH and CHCl₃ at the room temperature. The phosphoryl group participation was the key step of the esterification. This type of reactions were proposed through an intermediate of mixed phosphoric-carboxylic anhydride that might provide a clue to the function of the phosphoryl group in the phosphorylated enzymes and in the prebiotic synthesis of protein.
- O-Phosphoryl serine,
- self esterification,
- phosphoryl group participation
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