Citation: Xiao Pei GUAN, Hong YAN, Jian Guang SUN, Yong Zhong YU. NOVEL OXIDATION OF HEXABENZYLHEXAAZA-ISOWURTZITANE BY Me₂CHNO₂/CuCl/Py/O₂[J]. Chinese Chemical Letters, ;1996, 7(6): 511-512. shu

NOVEL OXIDATION OF HEXABENZYLHEXAAZA-ISOWURTZITANE BY Me₂CHNO₂/CuCl/Py/O₂

School of Chemical Engineering and Materials Science,Beijing Institute of Technology,Beijing,100081

Received Date: 9 January 1996

Fund Project: We are grateful to Dr. Zi-Jian Zeng for helpful discussions.

Treatment of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo-[5.5.0.0^3.9.0^3.11]dodecane (1) with Me₂CHNO₂/CuCl/Py/O₂ results in C (1)-C (7); oxidative cleavage to give 1,3.4,5,7,8-hexabenzyt-2,6-dioxo-cis-cisoid-cis-decahydro-1H,5H-diimidazo [4,5-b:4',5'-e] pyrazine (2).
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