Citation: Lan Ying ZHU, Jian Min DOU, Ying LIU, De Zhi SUN, Pei Ju ZHENG, Chen Xia DU, Yu ZHU. The Novel Benzo-15-Crown-5 with Palladium(II) Complex:[Na(B15C5)]₂[Pd(SCN)₄][J]. Chinese Chemical Letters, ;2000, 11(9): 835-838. shu

The Novel Benzo-15-Crown-5 with Palladium(II) Complex:[Na(B15C5)]₂[Pd(SCN)₄]

a Department of Biology and Chemistry, Liaocheng Teacher's University, Liaocheng 252000;
b Research Center of Analysis and Measurement, Fudan University, Shanghai 200433;
c Key Laboratory of Applied Chemistry, Zhengzhou University, Zhengzhou 450052

Received Date: 7 March 2000

A novel Pd (Ⅱ) Benzo-15-crown-5 complex[Na (B15C5)]₂[Pd (SCN)₄] has been isolated and characterized by IR and X-ray diffraction analysis.The crystal structure belongs to monoclinic, space group P2₁/n with cell dimensions, a=1.0164 (6), b=1.3743 (3), c=1.4987 (7) nm, β=95.248 (6)°, V=2.0847nm³, Z=2, F (000)=944, R=0.053, Rw=0.072.The compound consists of two[Na (B15C5)]⁺ complex cations and a [Pd (SCN)₄]^2- complex anion.Each sodium ion is coordinated by five crown ether oxygen atoms and one N atom from the SCN group of[Pd (SCN)₄]^2- to form stable neutral complex.
- Benzo-15-crown-5,
- crown ether,
- crystal structure,
- palladium complex
1. [1]
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2. [2]
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3. [3]
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4. [4]
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5. [5]
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6. [6]
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7. [7]
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8. [8]
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9. [9]
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11. [11]
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12. [12]
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13. [13]
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14. [14]
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15. [15]
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16. [16]
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17. [17]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
18. [18]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
19. [19]
  Hailong He , Wenbing Wang , Wenmin Pang , Chen Zou , Dan Peng . Double stimulus-responsive palladium catalysts for ethylene polymerization and copolymerization. Chinese Chemical Letters, 2024, 35(7): 109534-. doi: 10.1016/j.cclet.2024.109534
20. [20]
  Gongcheng Ma , Qihang Ding , Yuding Zhang , Yue Wang , Jingjing Xiang , Mingle Li , Qi Zhao , Saipeng Huang , Ping Gong , Jong Seung Kim . Palladium-free chemoselective probe for in vivo fluorescence imaging of carbon monoxide. Chinese Chemical Letters, 2024, 35(9): 109293-. doi: 10.1016/j.cclet.2023.109293