Citation: Shi Guo SUN, Xiao Jun PENG, Ming Wen FAN, Yong Qian XU, Lei SHI, Li Cheng SUN. Synthesis of Two Novel Rhenium (Ⅰ) Bipyridyl Photosensitive Dyes[J]. Chinese Chemical Letters, ;2004, 15(8): 965-968. shu

Synthesis of Two Novel Rhenium (Ⅰ) Bipyridyl Photosensitive Dyes

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012

Received Date: 21 July 2003

Fund Project: The authors would like to thank "973 program" of the ministry of Science & Technology of China and National Natural Science Foundation of China (project 20128005 and 20376010)

Two novel rhenium(Ⅰ) 2,2'-bipyridyl complexes,[(4,4'-di-COOEt-bipy) Re(CO)₃ (NCCH₃)PF₆] and[(4,4'-di-COOEt-bipy) Re (CO)₃ (NCS)], a model complex[(4,4'-di-COOEt-bipy) Re (CO)₃ (pyridine)PF₆], were synthesized.Their ground state electronic spectra and emission spectra were measured in acetonitrile.The MLCT absorption maximum of the complex exhibited a considerable red shift as the ligand changed from pyridine to CNCH₃, or SCN.
- Rhenium(Ⅰ) 2,2'-bipyridyl complex,
- photosensitizer,
- red shift
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