Citation: Yao Zeng SHI, Ya Jing RONG, Wei Ping JIANG, Wan Fang LU, Hong Wen HU. REACTION OF ETHYL N-CYANOMETHYLBENZEHECARBOXIMIDATE WITH ALIPHATIC ALDEHYDES UNDER THE SOLID-LIQUID PHASE TRANSFER CATALYSIS[J]. Chinese Chemical Letters, ;1991, 2(3): 213-216. shu

REACTION OF ETHYL N-CYANOMETHYLBENZEHECARBOXIMIDATE WITH ALIPHATIC ALDEHYDES UNDER THE SOLID-LIQUID PHASE TRANSFER CATALYSIS

Department of Chemistry, Nanjing University, Nanjing 210008

Received Date: 5 November 1990

Fund Project: The project supported by the National Natural Science Foundation of China.

Ethyl N-cyanomethytbenzenecarboximidate reacted with aliphatic aldehydes under the solid-liquid PTC condition to gire α-ethoxyphenylmethylene-aminoacrylonitrile derivatives and oxazoline derivatives. It is a convenient and new method for synthesis of β, β'-dihyroxy-α-amino acids by hydrolysis of the oxazoline derivatives.
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