Citation: Fu Xin XIE, Guang YANG, Shi Sheng NI. A NOVEL THIOPHENE-DERIVED N₂O₂ MACROCYCLEAND ITS Ag(Ⅰ) COMPLEX: SYNTHESIS AND CHARACTERIZATION[J]. Chinese Chemical Letters, ;1993, 4(1): 61-62. shu

A NOVEL THIOPHENE-DERIVED N₂O₂ MACROCYCLEAND ITS Ag(Ⅰ) COMPLEX: SYNTHESIS AND CHARACTERIZATION

Fu Xin XIE ^1,2 ,
Guang YANG ^1,2 ,
Shi Sheng NI ^1,2

1.
Department of Chemistry, Anhui University, Hefei 230039;
2.
National Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210008

Received Date: 19 August 1992

A novel macrocycle containing thiophene (L) was prepared first by the interaction of 2,5-bis-(chloromethyl)-thiophene (A) and salicylaldehyde to give 2, 5-bis-(2-formylphenoxymethyl)-thiophene (B), and then by the nontemplate cyclocondensation of 1,3-diaminopropane with (B) followed by a "onepot" reduction without isolation of the diimine intermediate. The corresponding silver complex, AgLClO₄, was also prepared. The macrocycle was characterized by IR, elemental analysis, MS and ¹HNMR
1. [1]
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2. [2]
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3. [3]
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8. [8]
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12. [12]
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13. [13]
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14. [14]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
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