Citation: . THE HYDROSILATION REACTION OF LADDERLIKE POLYALLYLSILSESQUIOXANE(ALLYL-T)AND POLYHYDROSILSESQUIOXANE(H-T)*[J]. Chinese Journal of Polymer Science, ;2002, 20(1): 31-38. shu

THE HYDROSILATION REACTION OF LADDERLIKE POLYALLYLSILSESQUIOXANE(ALLYL-T)AND POLYHYDROSILSESQUIOXANE(H-T)*

Received Date: 19 February 2001
Revised Date: 10 April 2001

The one plus one (1 + 1) mode of hydrosilation reaction of ladderlike cis-isotatic polyallylsilsesquioxane (Allyl-T)and polyhydrosilsesquioxane (H-T) using dicyclopentadienylplatinumdichloride (Cp2PtCl2) as the catalyst leads to theformation of a new polyorganosiloxane (POS). The presence of nanoscale tubular structure in the product POS waspreliminarily proved by IR, 1H-NMR, differential scanning calorimetry (DSC), X-ray diffraction (XRD), gel permeation chromatography (GPC), atomic force microscopy(AFM)and molecular simulation.
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