Citation: Mei Zhong JIN, Li YANG, Long Ming WU, You Chen LIU, Zhong Li LIU. Photochemical Reduction of Aromatic Imines by 2-Phenyl-N, N-dimethylbenzimidazoline[J]. Chinese Chemical Letters, ;2001, 12(4): 307-308. shu

Photochemical Reduction of Aromatic Imines by 2-Phenyl-N, N-dimethylbenzimidazoline

National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000

Received Date: 7 July 2000

Fund Project: The authors thank the National Natural Science Foundation of China (Grant No. 29972018) for financialsupport.

A series of aromatic imines were reduced to corresponding amines in excellent yields by 2-phenyl-N, N-dimethylbenzimidazoline (PDMBI) photochemically in the presence of magnesium perchloride (Mg(ClO₄)₂). A Mg²⁺ mediated photoinduced electron transfer mechanism was proposed.
- Photoinduced electron transfer,
- selective reduction,
- imine,
- PDMBI.
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