Citation: Yan CAI, Ming Qing CHEN, Juan XU, Pin Fang WU, Akashi MITSURU, Xiao Hua HUANG. Synthesis and Characterization of Samarium (Ⅲ) Containing Poly-(N-vinylacetamide) Complex[J]. Chinese Chemical Letters, ;2004, 15(9): 1109-1112. shu

Synthesis and Characterization of Samarium (Ⅲ) Containing Poly-(N-vinylacetamide) Complex

1.
School of Chemistry and Material Engineering, Southern Yangtze University, Wuxi 214036;
2.
College of Chemistry and Environment Science, Nanjing Normal University, Nanjing 210976;
3.
Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering, Kagoshima University, 1-21-40 Korimoto, Kagoshima 890-0065, Japan

Received Date: 18 August 2003

Fund Project: This project is supported by the National Natural Science Foundation of China (No.20243002), National Planning Commission Foundation of China (No.GJXOl 100626), the Foundation of Science and Technology Committee of Jiangsu Province (No.BG2001045) and the Natural Science Foundation of Education Committee of Jiangsu Province (01KJB150006).

Poly (N-vinylacetamide) (PNVA) was synthesized by the free radical polymerization and its samarium (Ⅲ) binary complex was prepared and characterized by means of IR, UV-vis, X-ray photoelectron spectroscopy (XPS) and fluorescence spectra. The fluorescent intensity of samarium (Ⅲ) characteristic emission was increased significantly due to efficient energy transfer from polymeric ligand to Sm (Ⅲ) ion in the complex.
- Samarium,
- poly (N-vinylacetamide),
- complex,
- fluorescence
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