Citation: Ji Ming ZHANG, Yong Min ZHANG. Catalytic HgCl₂-Samarium System Induced Reductive Coupling of Nitriles with Nitro Compounds[J]. Chinese Chemical Letters, ;2002, 13(2): 97-100. shu

Catalytic HgCl₂-Samarium System Induced Reductive Coupling of Nitriles with Nitro Compounds

Ji Ming ZHANG ^1, ,
Yong Min ZHANG ^1,2

1.
Department of Chemistry, Zhejiang University (Campus Xixi), Hangzhou 310028;
2.
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received Date: 12 June 2001

Fund Project: We thank the National Natural Science Foundation of China (Project No.20072033) and Natural Science Foundation of Zhejiang province for financial support.

The intermolecular coupling of a nitro group with a cyano group mediated by a Sm(Hg) amalgam prepared from metal samarium powder and catalytic mercury dichloride was studied.
- Mercury dichloride,
- samarium,
- reductive coupling,
- nitro group,
- cyano group,
- amidine
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