Citation: Guo Xiang XIONG, Jian Ping YE, Hui Jun XU. Spectroscopic Properties of a Novel Zinc Phthalocyanine with four 17-Membered Crown Ether Voids[J]. Chinese Chemical Letters, ;1997, 8(3): 239-242. shu

Spectroscopic Properties of a Novel Zinc Phthalocyanine with four 17-Membered Crown Ether Voids

Institute of Photographic Chemistry, Academia Sinica, P. O. Box 772, Beijing 100101

Received Date: 28 October 1996

Fund Project: This work is supported by the National Natural Science Foundation of China.

A zinc phthalocyanine containing (17-crown-5) ether subunits has been synthesized.UV-visible absorption and fluorescence emission spectra and associated photophysical parameters have been determined.In addition to the fluorescence at 710 nm from S₁.a strong upper excited state emission around 424 nm has been detected.X-ray structural analysis showed that the crown ether unit is conformationally deformed and oblate like that accounted for the unusual spectroscopic properties.
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