Citation: Lin Jing YANG, Xiao Yuan FU, Shao Wen ZHANG. THEORETICAL STUDIES ON NUCLEOPHILIC VINYLICHALIDE SUBSTITUTION[J]. Chinese Chemical Letters, ;1996, 7(7): 631-634. shu

THEORETICAL STUDIES ON NUCLEOPHILIC VINYLICHALIDE SUBSTITUTION

Department of Chemistry, Beijing Normal University, Beijing 100875

Received Date: 6 October 1995

Fund Project: Project supported by National Natural Science Foundation of China and State Educational Commission of China.

The reactions of vinyl fluoride, chloride, bromide and iodide with CN^- and OH^- were studied. The trend of reactivity of vinyl halide with these two nucleophile is:fluoroethene - tends to be a multi-step process while the reactions of the other three vinyl halides with CN^-. OH^- are all single-step processes. The nucleophilicity of CN^- is stronger than that of OH^-.
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