Citation: Cun Zhong ZHANG, Jing Lei LEI, Sheng Min CAI, He TIAN, Mai Zhi YANG. Study on the Electro-reduction of Perfluorodecalin[J]. Chinese Chemical Letters, ;2002, 13(7): 666-669. shu

Study on the Electro-reduction of Perfluorodecalin

1.
College of Chemistry & Molecular Engineering, Peking University, Beijing 100871;
2.
Institute of Fine Chemicals, East China University of Science & Technology, Shanghai 200237

Received Date: 26 June 2001
Revised Date: 13 March 2002

Fund Project: Project No.29877003 supported by the National Natural Science Foundation of China. The research Fund for Doctoral Program of Higher Education. Supported by the fund of state key laboratory for physical chemistry of solid surfaces. Partial supported by the laboratory of organic solids, Institute of Chemistry, Academy of Sciences of China.

The reduction ofperfluorodecalin was studied by the method of electrochemistry. The results indicated that the electrochemical reduction of perfluorodecalin was a multi-step reaction.The mechanism of the first consecutive reaction showed that it is to diffusion controlling step.
- Electrochemical reduction,
- perfluorocarbons compounds,
- electrocatalytic,
- organome tallic compounds
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