Citation: Xiao Lin SUN, Gut Lan ZHANG, Guo Qing TANG, Wen Ju CHEN, Guang Yan HONG. The Site Symmetry of Eu³⁺ in ZnS:Eu Nanoparticle[J]. Chinese Chemical Letters, ;1999, 10(9): 807-810. shu

The Site Symmetry of Eu³⁺ in ZnS:Eu Nanoparticle

Opto-electronic Information Science and Technology Lab, MOE,, Institute of Modern Optics, Nankai University, Tianjin 300071;
2.
Changchun Institute of Applied Chemistry, Changchun 130022

Received Date: 26 March 1999

Fund Project: This work was supported by the National Natural Science Foundation of China (NO. 59672015) and the Research Found of the Doctoral Program of Higher Education of China.

Nanosized ZnS doped with different concentrations of Eu³⁺ were prepared and analyzed by x-ray diffraction technique. The experimental results show that ZnS belongs to the cubic structure. From the photoluminescence (PL) emission spectra, it can be seen that the ratio of the emission intensity of Eu³⁺ at 616 nm to that at 590 nm increases as the increasing of Eu³⁺. This phenomenon reveals that the site symmetry of Eu³⁺ reduces as the increasing of Eu³⁺.
- ZnS:Eu nanoparticle,
- photoluminescence emission spectra,
- site symmetry
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16. [16]
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20. [20]
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