Citation: Zhou Bin YUAN, Yong CHEN Ping, REN Feng, Mei HAN. MICELLAR　ELECTROKINETIC　CAPILLARY　CHROMATOGRAPHIC　SEPPATION　OF　PYRIMIDINE　AND　PURINE　DERIVATIVES[J]. Chinese Chemical Letters, ;1996, 7(4): 347-350. shu

MICELLAR　ELECTROKINETIC　CAPILLARY　CHROMATOGRAPHIC　SEPPATION　OF　PYRIMIDINE　AND　PURINE　DERIVATIVES

The Graduate School, USTC, Academia Sinica, Beijing 100039

Received Date: 7 July 1995

Fund Project: The Postdoctoral Foundation of P. R. China is gratefully acknowledged for the support of this subject.

The retention behaviours of 12 purine and pyrimidine derivatives——thymine,uracil,cytosine,adenine,guanine,xanthine,hypoxanthine,purine,4,6-diaminopyrimidine,theophylline,trimethoprimum and 6-(benzylamino) purine,have been studied by micellar eiectrokinetic capillary chromatography (MECC).10 out of 12 analytes were separated by using 40 mmol/L sodium dodecyl sulfate-10 mmol/L borax-17% methanol-3.0 mmol/L β-cyclddextrin (pH 9.30) as electrolyte.The relative standard deviations (RSD) of t_R and UV absorbance were less than 1.8% and 6.5% (n=6),respectively.
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