Citation: Wen Jun CHEN, Gan Zuo LI, Li Min ZHAI, Bo Qin LI, Jun XU, Rui XIA. Spontaneous Vesicle Formation in Mixed Aqueous Solution of Poly-tailed Cationic and Anionic Surfactants[J]. Chinese Chemical Letters, ;2003, 14(3): 327-330. shu

Spontaneous Vesicle Formation in Mixed Aqueous Solution of Poly-tailed Cationic and Anionic Surfactants

Wen Jun CHEN ^1, ,
Gan Zuo LI ¹ ,
Li Min ZHAI ² ,
Bo Qin LI ³ ,
Jun XU ⁴ ,
Rui XIA ⁵

1.
Key Lab for Colloid and Interface Chemistry of State Education Ministry, Shandong University, Ji'nan 250100;
2.
Department of Chemistry, Jinan University, Ji'nan 250014;
3.
School of Medicine, Shandong University, Ji'nan 250012;
4.
Research Institution of Jinling Petrochemical Corporation, Nanjing 210046;
5.
Beijing Municipal Institute of Drug Control, Beijing 100035

Received Date: 8 May 2002

Fund Project: The work was supported by the Natural Science Foundation of China (No. 29903006, 29973023).

Spontaneous vesicles from the mixed aqueous solution of poly-tailed cationic surfactant PTA and anionic surfactant AOT are firstly obtained. Vesicle formation and characterizations are demonstrated by negative-staining TEM and dynamic light scattering. A monodisperse vesicle system is obtained with a polydispersity of 0.082. Ultrasonication can promote the vesicle formation. Mechanism of vesicle formation is discussed from the viewpoint of molecular interaction.
- Vesicle,
- dynamic light scattering,
- negative-staining TEM,
- spontaneous formation
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