Citation: CHEN Wu-Hua, ZHANG Zhu-Sen, HU Zhi-Biao, MI Jin-Xiao. The First Hybrid Wells-Dawson-type Polytungstate Monosupported by Cd-coordination Complex via Di-bridging O-atom[J]. Chinese Journal of Structural Chemistry, ;2014, 33(10): 1550-1559. shu

The First Hybrid Wells-Dawson-type Polytungstate Monosupported by Cd-coordination Complex via Di-bridging O-atom

CHEN Wu-Hua ^a,b,c ,
ZHANG Zhu-Sen ^c ,
HU Zhi-Biao ^c ,
MI Jin-Xiao ^a,b,,

1.
a College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, China;
2.
b Fujian Provincial Key Laboratory of Advanced Materials, Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen, Fujian 361005, China;
3.
c College of Chemistry and Material Science, Longyan University, Longyan, Fujian 364000, China

Corresponding author: MI Jin-Xiao,
Received Date: 23 May 2014
Available Online: 27 June 2014
Fund Project:

Polyoxometalates (POMs) with Cd-coordination complexes acting as supporting units are rarely reported. The linkage of the supporting units with inorganic building block (polyanion) is generally established on terminal O-atoms, but scarcely via bridging O-atoms. By introducing liquid small organic molecule (pyridine, C₅NH₅) as assistant "structure-directing agent", we obtained a novel organic-inorganic hybrid polytungstate, (Hpy)₄[Cd(phen)₂(P₂W₁₈O₆₂)]·nH₂O (1, n≈3, py=pyridine, phen=1,10-phenanthroline), under hydrothermal conditions. The single-crystal X-ray diffraction analysis shows that 1 is the first compound containing an asymmetric heteropolyanion,[Cd(phen)₂(P₂W₁₈O₆₂)]^4-, a Wells-Dawson-type polyanion monosupported by Cd-coordination complex via di-bridging O-atoms.
- hybrid compound,
- Wells-Dawson-type,
- Cd-coordination complex,
- monosupported structure,
- bi-bridging O-atom
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