Citation: YANG Yan, LI Chang-Gui, LUO Xu-Jian, CEN Bo, LUO Zhi-Hui, LIU Rong-Jun, JIANG Yue-Xiu, LIANG Wei-Jiang. Synthesis, Crystal Structure and Characterization of a Ni(Ⅱ) Complex of Constructed 2,6-Bis(benzimidazol-2-yl)pyridine[J]. Chinese Journal of Structural Chemistry, ;2014, 33(10): 1545-1549. shu

Synthesis, Crystal Structure and Characterization of a Ni(Ⅱ) Complex of Constructed 2,6-Bis(benzimidazol-2-yl)pyridine

1.
a School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China;
2.
b School of Chemistry and Material, Yulin Normal University, Yulin 537000, China

Corresponding author: YANG Yan, LIANG Wei-Jiang,
Received Date: 6 April 2014
Available Online: 10 July 2014
Fund Project: This work was supported by the NNSFC (No. 21341005) (No. 21341005)

A fluorescent Ni(Ⅱ) complex 1,[Ni(OH-H₂Bdc)(Bibimp)]_n·nH₂O, constructed with 5-hydroxyisophthalic acid (OH-H₂Bdc) and 2,6-bis(2-benzimidazolyl)pyridine) (Bibimp) has been synthesized by hydrothermal methods and structurally characterized by elemental analysis, IR spectroscopy, TG/DTG, fluorescence spectrum and single-crystal X-ray diffraction. The title complex crystallizes in triclinic system, space group P1 with a=10.187(2), b=10.273(2), c=13.401(3) Å, α=69.65(3), β=69.66(3), γ=70.61(3)°, V=1196.8(4) Å³, and Z=2. The adjacent chains of complex 1 are stacked offset with respect to each other in an ABAB fashion by van der Waals interactions, and only a weak interlayer nonclassical C-H…O hydrogen bond has been observed. Complex 1 displays strong blue fluorescent emissions at 483 nm in the solid state upon photo-excitation at 365 nm at room temperature.
- nickel(Ⅱ) complex,
- thermal behaviour,
- fluorescence
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