Citation: LI Wei, LI Chang-Hong, LI Heng-Feng, TAN Xiong-Wen. Synthesis, Crystal Structure and Properties of a Copper Complex with the Bicycle[2.2.1]-2-heptene-5,6-dicarboxylic Acid[J]. Chinese Journal of Structural Chemistry, ;2014, 33(10): 1527-1532. shu

Synthesis, Crystal Structure and Properties of a Copper Complex with the Bicycle[2.2.1]-2-heptene-5,6-dicarboxylic Acid

LI Wei ^a,b ,
LI Chang-Hong ^c ,
LI Heng-Feng ^a,, ,
TAN Xiong-Wen ^a,b

1.
a School of Materials Science and Engineering, Central South University, Changsha 410083, China;
2.
b Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China;
3.
c Department of Chemical Engineering, Hunan Institute of Technology, Hengyang 421002, China

Corresponding author: LI Heng-Feng,
Received Date: 20 December 2013
Available Online: 17 July 2014
Fund Project: Supported by the Natural Science Foundation of Hunan Province (No.11JJ9006) (No.11JJ9006)the Construct Program of the Key Discipline in Hunan Province (2012FJ2002)

A new copper complex 2{Cu(C₁₀H₈N₂)[C₈H₁₁O₂(COO)](H₂O)₃}·(H₂O)₅ with bicycle[2.2.1]hept-2-en-5,6-dicarboxylic acid (H₂L)[C₇H₈(COOH)₂], basic copper carbonate and 2,2'-bipyridine has been synthesized in the mixed solvents of methanol and water. It crystallizes in the triclinic system, space group P1, with a=7.4626(5), b=11.9779(8), c=12.9841(8) Å, α=109.7040(10), β=98.7550(10), γ=90.6240(10)°, V=1077.50(12) Å³, D_c=1.538 g/cm³, Z=1, F(000)=520, GOOF=1.065, R=0.0360 and wR=0.0950. The copper ion is coordinated with four oxygen atoms from one H2L molecule and three water molecules together with two nitrogen atoms from the 2,2'-bipyridine molecule, forming a distorted octahedral coordination geometry. The thermal stability and electrochemical properties were also studied.
- copper(Ⅱ) complex,
- crystal structure,
- properties analysis
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