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Citation: YU Jiang-Xi, KUANG Dai-Zhi, FENG Yong-Lan, ZHU Xiao-Ming, JIANG Wu-Jiu, ZHANG Fu-Xing. Solvothermal Syntheses, Crystal Structures, Thermal Stability and Quantum Chemistry of Dinuclear Trialkyltin Complexes Constructed by Camphoric Acid[J]. Chinese Journal of Structural Chemistry, ;2014, 33(10): 1521-1526. shu

Solvothermal Syntheses, Crystal Structures, Thermal Stability and Quantum Chemistry of Dinuclear Trialkyltin Complexes Constructed by Camphoric Acid

1.
Key Laboratory of Functional Organometallic Materials of College of Hunan Province, Department of Chemistry and Material Science, Hengyang Normal University, Hengyang 421008, China

Received Date: 5 August 2013
Available Online: 17 July 2014
Fund Project: Supported by Natural Science Foundation of Hunan Province (No. 13JJ3112) (No. 13JJ3112) Scientific & Technological Projects of Hunan Province (No. 2013TZ2025, 2014NK3086) (No. 2013TZ2025, 2014NK3086) Open Foundation of Innovation Platform of Hunan Provincial University (No. 13K105, 14K014) (No. 13K105, 14K014) Scientific & Technological Projects of Hengyang City (No. 2012KJ30) (No. 2012KJ30) Cultivation projects Based on Collaborative Innovation Center of Hengyang Normal University (No.12XT02) (No.12XT02)the Youth Backbone Teacher Training Program of Hengyang Normal University (2012) (2012)

Two dinuclear organotin complexes C₈H₁₄(CO₂SnCy₃)₂ (1) (Cy=cyclohexyl group) and C₈H₁₄[CO₂Sn(CH₂CMe₂Ph)₃]₂ (2) were synthesized by the reactions of camphoric acid with tricyclohexyltin hydroxide and bis[tri(2-methyl-2-phenyl)propyltin] oxide under solvothermal conditions, and these complexes were characterized by infrared spectra, elemental analyses, and H NMR spectra. The crystal of 1 belongs to the monoclinic system, space group P2₁/c with a=1.83478(19), b=1.52707(18), c=1.9849(2) nm, β=122.515(7)°, Z=4, V=4.6896(9) nm³, D_c=1.324 g/cm³, μ(MoKα)=1.103 mm^-1, F(000)=1952, R=0.0697 and wR=0.2040. In addition, thermal stability and quantum chemical calculation of 1 were also studied.
- trialkyltin complex,
- camphoric acid,
- solvothermal synthesis,
- structure,
- quantum chemistry
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