Citation: XU Zhan-Lin, LIU Fu-Yi, XU Ye, WANG Jia, LI Yuan, WANG Xiu-Yan. Synthesis, Crystal Structure, Thermal Behavior and Photoluminescence of a Novel Two-dimensional Cd(Ⅱ) Coordination Polymer[J]. Chinese Journal of Structural Chemistry, ;2014, 33(10): 1516-1520. shu

Synthesis, Crystal Structure, Thermal Behavior and Photoluminescence of a Novel Two-dimensional Cd(Ⅱ) Coordination Polymer

XU Zhan-Lin ^a,b ,
LIU Fu-Yi ^a,b ,
XU Ye ^a,b ,
WANG Jia ^a,b ,
LI Yuan ^a,b ,
WANG Xiu-Yan ^a,b,,

1.
a Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, China;
2.
b College of Chemistry, Jilin Normal University, Siping 136000, China

Corresponding author: WANG Xiu-Yan,
Received Date: 12 February 2014
Available Online: 18 July 2014
Fund Project:

A new coordination polymer,[Cd₂(bptc)(L)₂(H₂O)₂]·5H₂O (1, L=2-(2-chloro-6-fluorophenyl)-1H-imidazo[4,5-f] [1,10]phenanthroline and H₄bptc=3,3',4,4'-biphenyltetracarboxylic acid), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group P2₁/n with a=18.868(4), b=7.2111(14), c=19.464(4) Å, β=95.75(3)°, C₅₄H₃₁Cd₂Cl₂F₂N₈O₁₅, M_r=1365.57, V=2635.0(9) Å³, Z=2, D_c=1.721 g/cm³, S=1.034, μ(MoKα)=0.995 mm^-1, F(000)=1358, R=0.0501 and wR=0.1076. In 1, each bptc anion bridges four Cd(Ⅱ) atoms to form 2D layer structures, which are further extended by π-π stacking interactions into a 3D supramolecular architecture. The thermal behavior and luminescent properties of the compound have also been studied.
- crystal structure,
- coordination polymer,
- 1,10-phenanthroline derivative,
- 3,3',4,4'-biphenyltetracarboxylic acid
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