Citation: Ahmad Poursattar Marjania, Bayram Parsa Habashi, Hojjatollah Rahchamani, Jabbar Khalafy, Alireza Dadrass, Hooman Yaghoobnejad Asl. Synthesis of Quinoxalinophenazine Derivatives and Reaction of 3,12-Dimethylbenzo[a]quinoxalino-[2,3-c]phenazine with Mercury(Ⅱ) Bromide:Spectral and Structural Characterization[J]. Chinese Journal of Structural Chemistry, ;2014, 33(10): 1460-1466. shu

Synthesis of Quinoxalinophenazine Derivatives and Reaction of 3,12-Dimethylbenzo[a]quinoxalino-[2,3-c]phenazine with Mercury(Ⅱ) Bromide:Spectral and Structural Characterization

1.
a Department of Chemistry, Faculty of Science, Urmia University, Urmia 57154, Iran;
2.
b Department of Chemistry, Missouri University of Science and Technology, Rolla, MO 65409, USA

Corresponding author: Bayram Parsa Habashi,
Received Date: 31 March 2014
Available Online: 28 August 2014

A new series of quinoxalinophenazine derivatives were synthesized in good yields by the reaction of 2,3-dibromonaphthalene-1,4-dione with different aryl-1,2-diamines in DMF as solvent at 120~130℃ or under reflux conditions. 3,12-dimethylbenzo[a]quinoxalino[2,3-c] phenazine with bidentate character reacts with mercury(Ⅱ) bromide to give suitable crystals. All products were confirmed by IR, ¹H and ¹³C NMR, and the metal complex by single-crystal X-ray method. The crystal (C₂₄H₁₆Br₂HgN₄, M_r=720.82) belongs to the triclinic system, space group P1 with a=10.186(6), b=10.421(6), c=11.470(7) Å, α=98.670(7), β=95.069(7), γ=109.831(7)°, V=1119.4(12) Å³, Z=2, D_c=2.139 Mg/m³, μ=10.46 mm^-1, F(000)=676, R=0.043 and wR=0.115 for 3982 observed reflections with I>2σ(I).
- aryl-1,2-diamines,
- 2,3-dibromonaphthalene-1,4-dione,
- mercury complexes,
- quinoxalinophenazine derivatives,
- N,N-chelating
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