Citation: ZHAI Lian-Jie, WAGN Bo-Zhou, FAN Xue-Zhong, LI Xiang-Zhi. Synthesis, Crystal Structure and Thermal Decomposition of a New Energetic Potassium Salt of Bis(dinitromethyl)difurazanyl Ether[J]. Chinese Journal of Structural Chemistry, ;2014, 33(9): 1353-1359. shu

Synthesis, Crystal Structure and Thermal Decomposition of a New Energetic Potassium Salt of Bis(dinitromethyl)difurazanyl Ether

1.
Xi'an Modern Chemistry Research Institute, Xi'an 710065, China

Received Date: 19 February 2014
Available Online: 15 April 2014
Fund Project: Project supported by the National Natural Science Foundation of China (No. 21243007) (No. 21243007)National Defense Fundamental Scientific Research (No. B09201100051) (No. B09201100051)

A new energetic organic potassium salt bis(dinitromethyl)difurazanyl ether potassium salt[K₂(BDFE)] was synthesized, and structurally characterized by elemental analysis, IR spectra, ¹³C NMR and single-crystal X-ray diffraction. K₂(BDFE) crystallizes in monoclinic system, space group C2/c with a=17.342(3), b=12.6943(17), c=8.0972(11) Å, β=110.630(2)°, V=1668.3(4) Å³, Z=4, Dc=2.000 g/cm³, F(000)=1000, μ=0.675 mm^-1, S=1.058, the final R=0.0499 and wR=0.1452. The K ion is eight-coordinated with eight O atoms from one water molecule and four bis(dinitromethyl)difurazanyl ethers (BDFE), forming a distorted dodecahedral structure. Thermal decomposition of the title complex was studied by using DSC and TG-DTG. There are primarily two exothermic decomposition processes between 200 and 370℃.
- bis(dinitromethyl)difurazanyl ether,
- synthesis,
- crystal structure,
- thermal decomposition
1. [1]
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18. [18]
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