Citation: MING Chun-Lun, MA Pei-Juan, LI Guang-Yue, CUI Guang-Hua. A Dinuclear Cu(Ⅱ)-based Coordination Framework with Two-fold Interpenetrated 3D pcu Topology Displaying Catalytic Activity[J]. Chinese Journal of Structural Chemistry, ;2014, 33(9): 1339-1345. shu

A Dinuclear Cu(Ⅱ)-based Coordination Framework with Two-fold Interpenetrated 3D pcu Topology Displaying Catalytic Activity

1.
College of Chemical Engineering, Hebei United University, Tangshan, Hebei 063009, China

Corresponding author: CUI Guang-Hua,
Received Date: 25 February 2014
Available Online: 10 June 2014
Fund Project: This project was supported by the Excellent Youth Fund of Hebei Province Department of Education (Y2012010) (Y2012010)

A new Cu(Ⅱ) coordination polymer,[Cu₂(mip)₂(bmix)]_n (bmix=1,4-bis(2-methylimidazole-1-ylmethyl)benzene, H₂mip=5-methylisophthalic acid), has been hydrothermally synthesized and characterized by elemental analyses, IR, TGA and single-crystal X-ray diffraction. The title compound belongs to the triclinic system, space group P1 with a=9.435(5), b=12.241(6), c=13.666(6) Å, β=94.396(8)°, V=1565.5(13) Å³, Z=2, C₃₄H₃₀Cu₂N₄O₈, M_r=749.70, Dc=1.590 g/cm³, μ=1.419 mm^-1 and F(000)=768. The title metal-organic coordination polymer exhibits the first two-fold interpenetrated pcu topological structure assembled by two types of dinuclear copper(Ⅱ) clusters and a flexible bis(imidazole)-based ligand. In addition, the fluorescence and catalytic performances of the complex for the degradation of Congo red azo dye in Fenton-like process were presented.
- catalysis,
- copper(Ⅱ) complex,
- flexible bis(imidazole),
- fluorescence property
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