Citation: Zhi LIU, Qi FANG, Wen Tao YU, Guo Qun LIU, Wen XU, Min Hua JIANG, Bin ZHANG, Dao Ben ZHU. The Inorganic-free Organic Conductor α'-(ET)₂C₆H₄(SO₃)₂:Its Synthesis, Structure, and Conductivity[J]. Chinese Chemical Letters, ;2002, 13(8): 725-728. shu

The Inorganic-free Organic Conductor α'-(ET)₂C₆H₄(SO₃)₂:Its Synthesis, Structure, and Conductivity

Zhi LIU ^1, ,
Qi FANG ¹ ,
Wen Tao YU ¹ ,
Guo Qun LIU ¹ ,
Wen XU ¹ ,
Min Hua JIANG ¹ ,
Bin ZHANG ² ,
Dao Ben ZHU ²

1.
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100;
2.
Institute of Chemistry, The Chinese Academy of Science, Beijing 100080

Received Date: 9 November 2001

Fund Project: This project was supported by a grant for the State Key Program of China and by the National Natural Science Foundation of China (No.20172034), and also supported by the open laboratory of organic solid of Institute of Chemistry of the Chinese Academy of Science.

A new ET based cation radical salt, α'-(ET)₂C₆H₄(SO₃)₂ (ET=bis(ethylenedithio) tetrathiafulvalene) has been synthesized by oxidative electro-crystallization and the crystal structure determined to be in monoclinic system, P2/n space group. Its resistivity-temperature curve shows a semi-conductive behavior with a discontinuation at about 150K.
- ET,
- synthesis,
- structure,
- conductivity
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