Citation: GAO Yan, FAN Li-Ming, SONG Wei-Kuo, LIU Xin-Zheng, ZHANG Xiu-Tang. Synthesis, Crystal Structure, and Topology Analysis of One Novel Interpenetrated 2D Cobalt Coordination Polymer, {[Co(HTCB)(4,4'-btb)]·H₂O}_n[J]. Chinese Journal of Structural Chemistry, ;2014, 33(9): 1333-1338. shu

Synthesis, Crystal Structure, and Topology Analysis of One Novel Interpenetrated 2D Cobalt Coordination Polymer, {[Co(HTCB)(4,4'-btb)]·H₂O}_n

1.
a Advanced Material Institute of Research, College of Chemistry and Chemical Engineering, Qilu Normal University, Jinan 250013, China;
2.
b State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China

Received Date: 6 April 2014
Available Online: 4 July 2014
Fund Project: This work was supported by the National Natural Science Foundation of China (20873150) (20873150)

One novel cobalt coordination polymer, {[Co(HTCB)(4,4'-btb)]·H₂O}_n (1, H₃TCB=1,3,5-tris(4-carboxyphenyl)benzene, 4,4'-btb=4,4'-bis(1,2,4-triazol-3-yl)biphenyl), has been synthesized and characterized by elemental analysis, IR, powder X-ray diffraction (PXRD), and thermogravimetric (TG) analyses. X-ray diffraction analysis reveals that complex 1 is a 2D 2-fold interpenetrated {4⁴,6²}-sql[Co(HTCB)(4,4'-btb)] sheet based on the 1D[Co(HTCB)]_n chains and 1D[Co(4,4'-btb)]_n chains. The crystal of 1 crystallizes in triclinic, space group P1 with a=9.529(12), b=13.914(16), c=14.906(17) Å, V=1903(4) Å³, Z=2, C₄₅H₃₄N₆CoO₇, M_r=829.71, Dc=1.448 g/cm³, F(000)=858 and μ(MoKα)=0.514 mm^-1. The final R=0.0655 and wR=0.1136 for 6603 observed reflections with I > 2σ(I) and R=0.1136 and wR=0.1747 for all data.
- 1,3,5-tris(4-carboxyphenyl)benzene,
- 4,4'-bis(1,2,4-triazol-3-yl)biphenyl,
- cobalt,
- interpenetrated,
- topology
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