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Citation: ZHANG Zhi-Jian, KUANG Dai-Zhi, JIANG Wu-Jiu, YU Jiang-Xi, ZHU Xiao-Ming, ZHANG Fu-Xing. Synthesis, Crystal Structure, and Thermal Stability of a Dibutyltin Complex {[4-Et₂NC₆H₃(O)C=NC₆H₃(O)-5-NO₂](n-Bu₂Sn)}₂ and Its Interaction with DNA[J]. Chinese Journal of Structural Chemistry, ;2014, 33(9): 1319-1325. shu

Synthesis, Crystal Structure, and Thermal Stability of a Dibutyltin Complex {[4-Et₂NC₆H₃(O)C=NC₆H₃(O)-5-NO₂](n-Bu₂Sn)}₂ and Its Interaction with DNA

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a Department of Life Science, Hengyang Normal University, Hengyang 421008, China;
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b Department of Chemistry and Material Science, Key Laboratory of Functional Organometallic Materials of Hunan Provincial College, Hengyang Normal University, Hengyang 421008, China

Corresponding author: ZHANG Zhi-Jian,
Received Date: 2 December 2013
Available Online: 24 June 2014
Fund Project: This research was supported by the Natural Science Foundation of Hunan Province (No. 13JJ3112) (No. 13JJ3112) Scientific & Technological Projects of Hunan Province (No. 2013TZ2025, 2014FJ3060) (No. 2013TZ2025, 2014FJ3060) Scientific Research Fund of Hunan Provincial Education Department of China (14C0171) (14C0171) the Foundation of Key Laboratory of Functional Organometallic Materials, University of Hunan Province (No. 13K03, 13K04, 13K05) (No. 13K03, 13K04, 13K05)

The Schiff base organotin(IV) complex {[4-Et₂NC₆H₃(O)C=NC₆H₃(O)-5-NO₂](n-Bu₂Sn)}₂ has been synthesized via the reaction between 4-(diethylamino) salicylaldehyde-2-amino-4-nitrophenol Schiff base (H₂L) and dibutyltin oxide. Complex C1 has been characterized by IR, ¹H NMR, ¹³C NMR spectra, and elemental analysis, and its crystal structure was determined by X-ray diffraction. It crystallizes in the monoclinic system, space group P2₁/n with a=15.6559(8), b=9.1657(5), c=18.8351(10) Å, β=107.3440(10)°, Z=4, V=2579.9(2) Å³, Dc=1.442 Mg·m^-3, μ(MoKα)=1.025 mm^-1, F(000)=1152, R=0.0250 and wR=0.0633. The central Sn atom is coordinated in a hexadentate manner to assume a distorted octahedral configuration. Complex C1 was studied by TGA analysis in air atmosphere. The interaction between complex C1 and the herring sperm DNA was realized through the intercalation of the complex based on the studies by EB fluorescent probe.
- organotin complex,
- synthesis,
- crystal structure,
- thermal stability,
- DNA
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