Citation: SUN Zhi-Hao, WANG Yong, MA Xiao, WANG Yan-Long, HU Sheng-Min, SHENG Tian-Lu, WU Xin-Tao. Synthesis, Crystal Structure and MMCT Property of a New Mixed-valence Cyanide-bridged Binuclear Complex[J]. Chinese Journal of Structural Chemistry, ;2014, 33(9): 1305-1310. shu

Synthesis, Crystal Structure and MMCT Property of a New Mixed-valence Cyanide-bridged Binuclear Complex

SUN Zhi-Hao ^a,b ,
WANG Yong ^a,b ,
MA Xiao ^b ,
WANG Yan-Long ^a,b ,
HU Sheng-Min ^a ,
SHENG Tian-Lu ^a,, ,
WU Xin-Tao ^a

1.
a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
2.
b Graduate School of the Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: SHENG Tian-Lu,
Received Date: 24 March 2014
Available Online: 23 July 2014
Fund Project: This work was supported by the 973 Program (2012CB821702, 2014CB845603) (2012CB821702, 2014CB845603)

A new mixed-valence cyanide-bridged complex, Br₃Fe(μ-NC)RuBr(dppm)₂ (dppm=bis(diphenylphosphino)methane), was obtained through the reaction between trans-(dppm)₂ClRuCN and FeBr₃. Its crystal structure was characterized. Electronic absorption spectra indicate the existence of metal-to-metal charge transfer (MMCT) and this complex is Class Ⅱ mixed valence complexes according to the classification of Robin and Day. Magnetic analysis shows it is paramagnetic.
- cyanide-bridged,
- mixed-valence,
- binuclear,
- MMCT,
- crystal structure
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