Citation: WANG Cui-Cui, YANG Ge-Ge, LI Hai-Ye, JIANG Yi-Min. Synthesis and Crystal Structure of a Cu(Ⅱ) Coordination Polymer:[Cu(L)(1,10-phen)]_n[J]. Chinese Journal of Structural Chemistry, ;2014, 33(9): 1300-1304. shu

Synthesis and Crystal Structure of a Cu(Ⅱ) Coordination Polymer:[Cu(L)(1,10-phen)]_n

1.
a School of Chemistry and Pharmaceutical Sciences of Guangxi Normal University, Guilin 541004, China;
2.
b Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources of Guangxi Normal University, Guilin 541004, China

Corresponding author: LI Hai-Ye,
Received Date: 26 November 2013
Available Online: 15 July 2014
Fund Project: Ministry of Education of China (No. CMEMR2011-13) (Guangxi Normal University) and the Scientific research and technological development project of Guilin (No. 20110330) (No. CMEMR2011-13)

A new complex[Cu(L)(1,10-phen)]_n (1, L=N-3-pyridine sulfonyl amino acid) has been synthesized and characterized by IR, elemental analysis and X-ray diffraction analysis, and its crystal belongs to monoclinic, space group P2₁/c with a=11.481(2), b=18.094(4), c=8.5198(17) Å, β=102.26(3)°,V=1729.5(6) Å³, Z=4, Dc=1.759 g/cm³, F(000)=932, μ=1.422 mm^-1, R=0.0368 and wR=0.0893. In 1, the Cu(Ⅱ) ion adopts a slightly distorted five-coordinated square pyramidal geometry. The L^2- ligand adopts O of the carboxyl bridging adjacent Cu(Ⅱ) units to form an infinite chain structure along the c axis. Also, π-π stacking interactions between the adjacent chains expanded the 1-D structures into a 3-D supramolecular structure.
- coordination polymer,
- Cu(Ⅱ) complex,
- N-3-pyridine sulfonyl amino acid,
- crystal structure
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