Citation: QIN Xiao-Huan, ZOU Hua-Hong, GUI Liu-Cheng, LIAO Yong-Zhi, LI Hai-Ye, HUANG Fu-Ping. Crystal Structure and Luminescent Properties of a Zn(Ⅱ) Coordination Polymer Assembled by Mixed-ligand[J]. Chinese Journal of Structural Chemistry, ;2014, 33(9): 1293-1299. shu

Crystal Structure and Luminescent Properties of a Zn(Ⅱ) Coordination Polymer Assembled by Mixed-ligand

1.
a Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources School of Chemistry and Pharmacy, Guangxi Normal University, Guilin 541004, China;
2.
b Guangxi Academy of Fishery Sciences, Nanning 530021, China

Received Date: 18 January 2014
Available Online: 11 July 2014
Fund Project: Supported by the National Natural Science Foundattion of China (21101035) (21101035) Natural Science Foundattion of Guangxi province (2012GXNSFBA053017) (2012GXNSFBA053017)the Natural Science Foundation of Guangxi Normal University (CMEMR2013-A05)

A Zn(Ⅱ) coordination polymer[Zn(NIP)(3,3'-bpt)]·H₂O (1, NIP=5-nitroisophthalate, 3,3'-bpt=1H-3,5-bis(3-pyridyl)-1,2,4-triazolate) has been synthesized by the hydrothermal reaction at 140℃ and structurally characterized by IR spectroscopy, X-ray diffraction, thermal analysis, single-crystal X-ray diffraction and luminescent properties. In complex 1, the zinc atom is five-coordinated with three carboxylate oxygen atoms from three H₂NIP and two nitrogen atoms from two 3,3'-bpt, respectively, forming a distorted trigonal bipyramidal geometry and showing a 1D chain structure, which is further bridged by NIP to form a 3D supramolecular network via self-assembly of hydrogen bonds.
- Zn(Ⅱ) coordination polymer,
- crystal structure,
- luminescent properties
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